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Физическая химия

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Физическая химия

Intramolecular Cyclopropanation/Thermal Fragmentation strategy. Intramolecular Reactions of Diazo Compounds in Natural Product Synthesis

Формат:      Страниц 80
     мягкая обложка
Florence M.    
Книга по Требованию    
1997 руб
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The development of a novel methodology toward the construction of 5-7 ring systems. The substrate is subjected to the transition metal- catalyzed diazo decomposition conditions to afford the desired intramolecular cyclopropanation product. To expand the scope of these reactions to include additional functionality, a tethered diazo moiety has been attached onto the cyclobutene. The added functionality provides a handle for further manipulations for the synthesis of natural products with more structural complexity. These structures are accessed starting with the preparation of functionalized cyclobutenes and applying a new intramolecular cyclopropanation/thermal fragmentation strategy. These ring systems are skeletons of a versatile class of many natural products with diverse biological activities.
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Молочный гриб можно использовать для похудения, восстановления микрофлоры, очищения организмаМолочный гриб можно использовать для похудения, восстановления микрофлоры, очищения организма

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